Various experiments have indicated that electron transfer through nonmagnetic chiral hydrocarbon molecules is spin dependent. This property is called the chiral-induced spin selectivity (CISS)...Show moreVarious experiments have indicated that electron transfer through nonmagnetic chiral hydrocarbon molecules is spin dependent. This property is called the chiral-induced spin selectivity (CISS) effect and its presence cannot be explained with current theoretical models. To detect the CISS effect experimentally, chiral molecules have to be isolated. Therefore, transport through a single chiral molecule must be measured with STM. A fabrication procedure for sharp and stable nickel STM tips has been developed using electrochemical etching. The produced tips are very sharp and have an average opening angle of 18.9° and an apex size below 200 nm. The magnetic polarisation of the tip can be reversed in situ by a magnetic field, induced by a coil around the tip, which has been demonstrated. The quality and the magnetisation of the tips have been tested on HOPG, gold and nickel with STM. Clear large-scale images were obtained on all materials. Atomic resolution was obtained on HOPG. With these challenges resolved, STM measurements using a nickel tip with both magnetic polarisations can be performed in the study of single chiral molecules as spin filter and the investigation of the CISS effect.Show less
